Research data uranium(I) paper.zip (2.61 MB)
Download file

Research data for paper: Identification of oxidation state +1 in a molecular uranium complex

Download (2.61 MB)
dataset
posted on 26.09.2022, 15:12 authored by Richard LayfieldRichard Layfield, Luciano BarluzziLuciano Barluzzi, Sean R. Giblin, Akseli Mansikkamäki

Data for paper published in the Journal of the American Chemical Society. September 2022


X-ray crystallography CIF files, IR data, UV/vis data, magnetic measurement data


Abstract

The concept of oxidation state plays a fundamentally important role in defining the chemistry of the elements. In the f block of the periodic table, well-known oxidation states in compounds of the lanthanides include 0, +2, +3 and +4, and oxidation states for the actinides range from +7 to +2. Oxidation state +1 is conspicuous by its absence from the f-block elements. Here we show that the uranium(II) metallocene [U(η5-C5iPr5)2] and the uranium(III) metallocene [IU(η5-C5iPr5)2] can be reduced by potassium graphite in the presence of 2.2.2-cryptand to the uranium(I) metallocene [U(η5-C5iPr5)2]− (1) (C5iPr5 = pentaisopropylcyclopentadienyl) as the salt of [K(2.2.2-cryptand)]+. An X-ray crystallographic study revealed that 1 has a bent metallocene structure, and theoretical studies and magnetic measurements confirmed that the electronic ground state of uranium(I) adopts a 5f3(7s/6dz2)1(6dx2–y2/6dxy)1 configuration. The metal–ligand bonding in 1 consists of contributions from uranium 5f, 6d, and 7s orbitals, with the 6d orbitals engaging in weak but non-negligible covalent interactions. Identification of the oxidation state +1 for uranium expands the range of isolable oxidation states for the f-block elements and potentially signposts a synthetic route to this elusive species for other actinides and the lanthanides.


Funding

Isolobal Solutions to the Hysteresis Challenge in Single-Molecule Magnetism

Engineering and Physical Sciences Research Council

Find out more...

Metal-organic frameworks as platforms for air-stable organometallic single-molecule magnets

Engineering and Physical Sciences Research Council

Find out more...

History