University of Sussex
Browse

File(s) not publicly available

A 1,3-diaza-2,4-distannacyclobutanediide: Synthesis, structure, and bonding

journal contribution
posted on 2023-06-08, 00:52 authored by Hazel CoxHazel Cox, Peter B Hitchcock, Michael F Lappert, Luc J M Pierssens
A combined experimental and computational study throws light on the structure and bonding of the diamagnetic {(SnN)2} compound [{Sn{N(SiMe3)}Cl}2] (see picture), obtained from the reaction of [Sn{N(SiMe3}2)(µ-Cl)]2 with AgOCN.

History

Publication status

  • Published

Journal

Angewandte Chemie International Edition

ISSN

1433-7851

Publisher

Wiley

External DOI

Issue

34

Volume

43

Page range

4500-4504

Pages

5.0

Department affiliated with

  • Chemistry Publications

Notes

HC performed all theory and co-authored the paper in collaboration with MFL. Experiments by LJMP and MFL, crystallography PBH. First three-coordinate tin compound which is not ionic or free radical; confirmed by theory. Calculated NMR chemical shifts fundamental to interpretation of discrepancies between the solid-state and solution NMR spectroscopic data.

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

Usage metrics

    University of Sussex (Publications)

    Categories

    No categories selected

    Keywords

    Uncategorised value

    Licence

    Copyright not evaluated

    Exports

    RefWorks
    BibTeX
    Ref. manager
    Endnote
    DataCite
    NLM
    DC