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A Lewis-basic, Dionio-Substituted Phosphane

journal contribution
posted on 2023-06-07, 20:44 authored by Martyn P Coles, Peter B Hitchcock
Bis{guanidine} H2C{hpp}2[hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine] reacts with PPhCl2 to generate the dionio-substituted phosphane, [H2C{hpp}2PPh]2+[Cl]2 which, despite the formally dicationic phosphorus centre, forms an unprecedented coordination compound with platinum.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

13597345

External DOI

Issue

48

Volume

-

Page range

5229-5231

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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