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A Lewis-basic, Dionio-Substituted Phosphane
journal contribution
posted on 2023-06-07, 20:44 authored by Martyn P Coles, Peter B HitchcockBis{guanidine} H2C{hpp}2[hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine] reacts with PPhCl2 to generate the dionio-substituted phosphane, [H2C{hpp}2PPh]2+[Cl]2 which, despite the formally dicationic phosphorus centre, forms an unprecedented coordination compound with platinum.
History
Publication status
- Published
Journal
Chemical CommunicationsISSN
13597345External DOI
Issue
48Volume
-Page range
5229-5231Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes