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A Synthesis of an Ionomycin Calcium Complex
journal contributionposted on 2023-06-08, 09:19 authored by Zhangua Gao, Yingfa Li, John P Cooksey, Thomas N Snaddon, Stefan Schunk, Eddy Viseux, Stephen M McAteer, Philip J Kocienski
A Synthesis of an Ionomycin Calcium Complex Caught in the middle : The ionomycin calcium complex (see structure ; O red, Ca green) was the target of an approach featuring the efficient asymmetric syn- thesis of an allene by a copper(I)-mediated anti-selective SN2 reaction, a highly stereoselective gold(III)-catalyzed cycloisomerization of an a-hydroxyallene, and a Rh-catalyzed rearrangement of an a-diazo-b-hydroxyketone.
JournalAngewandte Chemie International Edition
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