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A magnetically highly frustrated CuII27 coordination cluster containing a Cu18 folded-sheet motif
journal contribution
posted on 2023-06-08, 20:16 authored by Irina A Kühne, George KostakisGeorge Kostakis, Christopher E Anson, Annie K Powell[CuII27(µ4-O)2(OH)13(OMe)7(vanox)10(NO3)8(OH2)2(MeOH)7](NO3)2·2H2O·11MeOH (1) was synthesised from Cu(NO3)2·3H2O and o-vanillin-oxime. Structural analysis shows a molecule composed of a Cu18 “folded-sheet” motif linked to a Cu9 bridging unit. The cluster is highly frustrated and has an S = 1/2 spin ground state.
History
Publication status
- Published
Journal
Chemical CommunicationsISSN
1359-7345Publisher
Royal Society of ChemistryExternal DOI
Issue
13Volume
51Page range
2702-2705Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
