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Comparison of the reactivity of the low buried-volume carbene complexes (ITMe)2Pd(PhC=CPh) and (ITMe)2Pd(PhN=NPh)

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posted on 2023-06-09, 12:36 authored by Melvyn B Ansell, Samantha K Furfari, Geoff Cloke, S Mark Roe, John SpencerJohn Spencer, Oscar Navarro
The novel Pd(0)-azobenzene complex (ITMe)2Pd(PhN=NPh) (5) (ITMe = 1,3,4,5-tetramethylimidazol 2-ylidene) has been isolated and characterized in the solid state and by cyclic voltammetry. Its reactivity towards E-E’ bonds (E, E’= Si, B, Ge) has been compared with that of the known palladium carbene complex (ITMe)2Pd(PhC=CPh) (2). Whereas 2 reacts with all E-E’ bonds studied, 5 only reacted with B-B and B-Si moieties, echoing our previous catalytic studies on azobenzenes.

Funding

Linearly Conjugated Phosphacarbon Organometallics; G1810; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/N016785/1

DTA - University of Sussex 2013 (EPSRC); G1142; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/L505109/1

History

Publication status

  • Published

File Version

  • Published version

Journal

Organometallics

ISSN

0276-7333

Publisher

American Chemical Society

External DOI

Issue

7

Volume

37

Page range

1214-1218

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2018-03-23

First Open Access (FOA) Date

2018-04-18

First Compliant Deposit (FCD) Date

2018-03-22

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    Licence

    CC BY 4.0

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