acs.organomet.8b00112.pdf (1.22 MB)
Comparison of the reactivity of the low buried-volume carbene complexes (ITMe)2Pd(PhC=CPh) and (ITMe)2Pd(PhN=NPh)
journal contribution
posted on 2023-06-09, 12:36 authored by Melvyn B Ansell, Samantha K Furfari, Geoff Cloke, S Mark Roe, John SpencerJohn Spencer, Oscar NavarroThe novel Pd(0)-azobenzene complex (ITMe)2Pd(PhN=NPh) (5) (ITMe = 1,3,4,5-tetramethylimidazol 2-ylidene) has been isolated and characterized in the solid state and by cyclic voltammetry. Its reactivity towards E-E’ bonds (E, E’= Si, B, Ge) has been compared with that of the known palladium carbene complex (ITMe)2Pd(PhC=CPh) (2). Whereas 2 reacts with all E-E’ bonds studied, 5 only reacted with B-B and B-Si moieties, echoing our previous catalytic studies on azobenzenes.
Funding
Linearly Conjugated Phosphacarbon Organometallics; G1810; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/N016785/1
DTA - University of Sussex 2013 (EPSRC); G1142; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/L505109/1
History
Publication status
- Published
File Version
- Published version
Journal
OrganometallicsISSN
0276-7333Publisher
American Chemical SocietyExternal DOI
Issue
7Volume
37Page range
1214-1218Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
