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Direct detection of individual bis(arene) rotational isomers in the gas phase by mass-analyzed threshold ionization spectroscopy
journal contribution
posted on 2023-06-08, 07:42 authored by Sergey Y Ketkov, Heinrich L Selzle, Geoff ClokeIt's a gas! Mass-analyzed threshold ionization (MATI) spectroscopy provides high-resolution ionization potentials and low-energy vibrational frequencies of individual conformers of jet-cooled [(¿6-PhMe)2Cr]. The signals arising from distinct structural isomers were identified on the basis of DFT calculations and comparison of the [(¿6-PhMe) 2Cr] and [(¿6-1,3-Me2C6H 4)(¿6-PhH)Cr] spectra (see picture). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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Publication status
- Published
Journal
Angewandte Chemie International EditionISSN
1433-7851Publisher
WileyExternal DOI
Issue
37Volume
46Page range
7072-7074Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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