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Fe(III)/Cu(II) mediated 5- and 6-exo oxidative ring expansion/cyclisation of cyclopropyl ethers: studies towards dictyol C and a-eudesmol
journal contributionposted on 2023-06-08, 19:30 authored by Kevin I Booker-Milburn, Brian Cox, Mick Grady, Frank Halley, Shaun Marrison
The outcome of oxidative ring expansion/cyclisation of cyclopropanes with a mixed Fe(III)/Cu(II) system was found to be dependent on the mode of cyclisation. When 6-exo cyclisation was attempted unusual products resulting from oxidation of ring opened primary radicals were obtained.
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