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Iron- and cobalt-catalyzed synthesis of carbene phosphinidenes
journal contribution
posted on 2023-06-09, 13:03 authored by Kuntal Pal, Oliver B Hemming, Benjamin M Day, Thomas Pugh, David J Evans, Richard LayfieldRichard LayfieldIn the presence of stoichiometric or catalytic amounts of [M{N(SiMe3)2}2] (M=Fe, Co), N-heterocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of the type (NHC)·PAr. The formation of (IMe4)·PMes (Mes=mesityl) is also catalysed by the phosphinidene-bridged complex [(IMe4)2Fe-(m-PMes)]2, which provides evidence for metal-catalysed phosphinidene transfer.
History
Publication status
- Published
File Version
- Published version
Journal
Angewandte Chemie International EditionISSN
1433-7851Publisher
WileyExternal DOI
Issue
5Volume
55Page range
1690-1693Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes