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Methimazole-Based Ionic Liquids
journal contribution
posted on 2023-06-08, 08:57 authored by Amal I Siriwardana, Ian CrossleyIan Crossley, Angel A J Torriero, Iko M Burgar, Noel F Dunlop, Alan M Bond, Glen B Deacon, Douglas R MacFarlaneThe alkylation reaction of 2-mercapto-1-methylimidazole 1a with iodoethane and chlorobutane produced S-alkylmethimazole halides 2a and 2b which were subjected to anion metathesis with two different metal salts (MA) to afford methimazole-based room-temperature ionic liquids 3a, 3b, and 3c in 82%, 85%, and 87% yields, respectively. S-Alkylation giving 2a and 2b suggests that methimazole reacts through the thione tautomer.
History
Publication status
- Published
Journal
The Journal of Organic ChemistryISSN
0022-3263Publisher
American Chemical SocietyExternal DOI
Issue
12Volume
73Page range
4676-4679Department affiliated with
- Chemistry Publications
Notes
'second author' two other experimentalists. IMB, NFD, AMB, GBD, DRM all 'management team'Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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