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Mn2 bis(pentalene): a mixed-spin bimetallic with two extremes of bonding within the same molecule
journal contributionposted on 2023-06-07, 21:54 authored by Geoff Cloke, Peter Hitchcock, Owen Summerscales, G Balazs, A Harrison, JC Green
Structural, magnetic and theoretical studies show that the bimetallic pentalene complex, Mn2(C8H41,4-SiiPr3)2, contains both high and low spin Mn(ii) in two very different sites. © The Royal Society of Chemistry.
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