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Neighbouring group participation in the methanolysis of a vicinal diepoxide
journal contribution
posted on 2023-06-07, 20:19 authored by James R Hanson, Peter B Hitchcock, Ismail KiranThe tetracyanoethylene catalysed methanolysis of 17ß-acetoxy-4ß,5ß:6a,7a-diepoxyandrostane afforded 17ß-acetoxy-4a,7a-oxido-5ß-hydroxy-6ß-methoxyandrostane in which the methanolysis product of the 6a,7a-epoxide has participated in the cleavage of the 4ß,5ß-epoxide; the reaction is modified however by an adjacent 3ß-hydroxy group.
History
Publication status
- Published
Journal
Journal of Chemical Research, SynopsesISSN
0308-2342Publisher
RSC PublishingExternal DOI
Volume
6Page range
356 - 357ISBN
0308-2342Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes