Novel formation of a phenylated isoquinolino[3 ',4 ': 1,2][60]fullerene

Abdul-Sada, Ala'a; Avent, Anthony G; Birkett, P R; Darwish, Adam D; Kroto, Harold W; Taylor, Roger; Walton, David R M; Woodhouse, Oliver B

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Novel formation of a phenylated isoquinolino[3 ',4 ': 1,2][60]fullerene

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posted on 2023-06-07, 20:26 authored by Ala'a Abdul-Sada, Anthony G Avent, P R Birkett, Adam D Darwish, Harold W Kroto, Roger Taylor, David R M Walton, Oliver B Woodhouse

Reaction of C60Ph5Cl With cyanogen bromide results in replacement of the chlorine by BrCN and ring closure between the addend and an adjacent phenyl ring, giving a 1-bromoisoquinoline derivative of [60]fullerene; this readily undergoes nucleophilic replacement of Br by OH to give the corresponding 1-isoquinolone derivative.

History

Publication status

Published

Journal

Chemical Communications

ISSN

1359-7345

Publisher

Royal Society of Chemistry

Publisher URL

http://pubs.rsc.org/en/content/articlelanding/1998/cc/a707430a

External DOI

https://doi.org/10.1039/A707430A

Issue

3

Page range

307-308

Department affiliated with

Chemistry Publications

Full text available

No

Peer reviewed?

Yes

Legacy Posted Date

2012-02-06

File(s) not publicly available

Novel formation of a phenylated isoquinolino[3 ',4 ': 1,2][60]fullerene

History

Publication status

Journal

ISSN

Publisher

Publisher URL

External DOI

Issue

Page range

Department affiliated with

Full text available

Peer reviewed?

Legacy Posted Date

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