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Novel formation of a phenylated isoquinolino[3 ',4 ': 1,2][60]fullerene
journal contribution
posted on 2023-06-07, 20:26 authored by Ala'a Abdul-Sada, Anthony G Avent, P R Birkett, Adam D Darwish, Harold W Kroto, Roger Taylor, David R M Walton, Oliver B WoodhouseReaction of C60Ph5Cl With cyanogen bromide results in replacement of the chlorine by BrCN and ring closure between the addend and an adjacent phenyl ring, giving a 1-bromoisoquinoline derivative of [60]fullerene; this readily undergoes nucleophilic replacement of Br by OH to give the corresponding 1-isoquinolone derivative.
History
Publication status
- Published
Journal
Chemical CommunicationsISSN
1359-7345Publisher
Royal Society of ChemistryExternal DOI
Issue
3Page range
307-308Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes