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Novel formation of a phenylated isoquinolino[3 ',4 ': 1,2][60]fullerene

journal contribution
posted on 2023-06-07, 20:26 authored by Ala'a Abdul-Sada, Anthony G Avent, P R Birkett, Adam D Darwish, Harold W Kroto, Roger Taylor, David R M Walton, Oliver B Woodhouse
Reaction of C60Ph5Cl With cyanogen bromide results in replacement of the chlorine by BrCN and ring closure between the addend and an adjacent phenyl ring, giving a 1-bromoisoquinoline derivative of [60]fullerene; this readily undergoes nucleophilic replacement of Br by OH to give the corresponding 1-isoquinolone derivative.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

1359-7345

Publisher

Royal Society of Chemistry

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External DOI

Issue

3

Page range

307-308

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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    University of Sussex (Publications)

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