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On the structure of liquid hydrogen fluoride
journal contribution
posted on 2023-06-07, 19:45 authored by Sylvia E McLain, Chris J Benmore, Joan E Siewenie, Jacob Urquidi, John TurnerJohn TurnerShort, bent, strongly hydrogen-bonded chains, with strong interchain interactions and very little branching are the basis of the structure of liquid hydrogen fluoride (see picture), as determined at the partial radial distribution function level.
History
Publication status
- Published
Journal
Angewandte Chemie International EditionISSN
1433-7851External DOI
Issue
15Volume
43Page range
1952-1955Pages
4.0Department affiliated with
- Chemistry Publications
Notes
First determination of the structure of hydrogen fluoride at the atomic pair level, using neutron and high energy X-ray diffraction which showed that, contrary to calculations the structure is composed of finite chains, with an exceptionally short bent intermolecular hydrogen bond. JFCT directed the work and is corresponding author.Full text available
- No
Peer reviewed?
- Yes
