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On the structure of liquid hydrogen fluoride

journal contribution
posted on 2023-06-07, 19:45 authored by Sylvia E McLain, Chris J Benmore, Joan E Siewenie, Jacob Urquidi, John TurnerJohn Turner
Short, bent, strongly hydrogen-bonded chains, with strong interchain interactions and very little branching are the basis of the structure of liquid hydrogen fluoride (see picture), as determined at the partial radial distribution function level.

History

Publication status

  • Published

Journal

Angewandte Chemie International Edition

ISSN

1433-7851

Issue

15

Volume

43

Page range

1952-1955

Pages

4.0

Department affiliated with

  • Chemistry Publications

Notes

First determination of the structure of hydrogen fluoride at the atomic pair level, using neutron and high energy X-ray diffraction which showed that, contrary to calculations the structure is composed of finite chains, with an exceptionally short bent intermolecular hydrogen bond. JFCT directed the work and is corresponding author.

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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