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Photosolvolysis reactions of 3-alkoxypyridinium tetraflouroborate salts
journal contributionposted on 2023-06-07, 20:57 authored by Clive S Penkett, Iain D Simpson
Irradiation of a series of 3-alkoxypyridinium tetrafluoroborate salts in alcohol solution resulted in the formation of cyclopentenone ketals by diastereoselective incorporation of the alcohol solvent under the basic conditions of the photolysis reaction. In a second series of photochemical reactions, the same 3-alkoxypyridinium salts were irradiated in water to yield ß-hydroxycyclopentanones stereoselectively.
Page range6183 - 6204
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