Projection-operator route to the generalized darken equation
journal contribution
posted on 2023-06-08, 18:28authored byR Ferrando, Enrico Scalas, M Torri
The generalized Darken equation (GDE) for collective diffusion in lattice gases is derived in the framework of the Mori projection-operator technique. It is shown that the GDE is obtained if the dynamical correlations between successive transitions in the lattice gas are not taken into account.