File(s) not publicly available
Spontaneous assembly of a nine-vertex lithium framework encapsulating the peroxide dianion
journal contribution
posted on 2023-06-07, 19:34 authored by Martyn P Coles, Peter B HitchcockInvestigation of the structure of the lithiated bicyclic guanidine 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) has led to the reproducible isolation of compounds containing the 'Li-9(hpp)(7)(O-2)' core, in which a peroxide dianion has been encapsulated within a mono-capped, cubic array of lithium ions.
History
Publication status
- Published
Journal
Chemical CommunicationsISSN
1359-7345External DOI
Volume
25Page range
3165 - 3167Pages
3.0Department affiliated with
- Chemistry Publications
Notes
MPC performed all synthetic work and is the corresponding author. The first time the peroxo-dianion has been encapsulated by lithium rather than forming oxide species. The first demonstration of larger interstitial ions within simple lithium-guanidinate cages.Full text available
- No
Peer reviewed?
- Yes
