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The sulfinyl moiety in Lewis base-promoted allylations
journal contribution
posted on 2023-06-08, 08:01 authored by J Robin Fulton, Lamin M Kamara, Simon C Morton, Gareth J RowlandsBy employing Senanayake's oxathiazolidine-2-oxide reagent, a collection of sulfinamides was prepared and provided the first examples of sulfinamides promoting the allylation of benzaldehyde and N-benzoylhydrazones with allyltrichlorosilane. The optimum sulfinamide-derived Lewis base promoter displays comparable activity to the best sulfinyl-based Lewis bases reported. The use of bis-sulfoxides is also discussed.
History
Publication status
- Published
Journal
TetrahedronISSN
0040-4020Publisher
ElsevierExternal DOI
Issue
45Volume
65Page range
9134-9141Pages
8.0Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes