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Titanium and niobium imido complexes derived from diamidoamine ligands

journal contribution
posted on 2023-06-07, 21:59 authored by Philip E Collier, Stephen M Pugh, Howard S C Clark, Jason B Love, Alexander J Blake, Geoff Cloke, Philip Mountford
New groups 4 and 5 imido complexes derived from the diamidoamine ligand Me3SiN(CH2CH2NSiMe3)2 (N2N) are described. Reactions of Li2[N2N] with [Ti(NR)Cl2(py)3] gave compound 1 in which the N2N ligand adopts a fac-coordination mode. With [Nb(N1-Bu)Cl3(py)2], two different Nb(V) products were formed.

History

Publication status

  • Published

Journal

Inorganic Chemistry

ISSN

00201669

External DOI

Issue

9

Volume

39

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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