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Transformation of Coordinated Dinitrogen by Reaction with Dihydrogen and Primary Silanes
journal contribution
posted on 2023-06-08, 09:17 authored by Michael D Fryzuk, Jason B Love, Steven J Rettig, Victor G Jr YoungThe reaction of dihydrogen with a side-on bound dinitrogen complex of zirconium was investigated. Instead of a displacement of the dinitrogen moiety, which is the common mode of reactivity, a complex containing both a bridging hydride and a bridging hydrazido unit with a nitrogen-hydrogen bond was observed. This reaction was extended to primary silanes to produce a species that contained a nitrogen-silicon bond. In addition, an intermediate in the dihydrogen addition has been structurally characterized as having a bridging dihydrogen unit
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- Published
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ScienceISSN
0036-8075External DOI
Volume
275Page range
1445 - 1447ISBN
0036-8075Department affiliated with
- Chemistry Publications
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- No
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- Yes
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2012-02-06Usage metrics
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