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[60]- and [70]Fullerenes are trifluoromethylated across 5 : 6-bonds

journal contribution
posted on 2023-06-07, 22:38 authored by Adam D Darwish, Anthony G Avent, Ala'a K Abdul-Sada, Roger Taylor
Trifluoromethylation of[60]- and [70]fullerenes occurs across both 6:6- and 5: 6- bonds giving unsymmetrical tetramethyl adducts having four contiguous CF3 groups; both fullerenes give bis adducts which do not involve 6: 6-addition, and unsymmetrical hexa-adducts (with contiguous CF3 groups) are also obtained from [60] fullerene.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

1359-7345

Publisher

Royal Society of Chemistry

Issue

12

Volume

21

Page range

1374-1375

Pages

12.0

Department affiliated with

  • Chemistry Publications

Notes

AAS performed the MS measurements in collaboration with the late RT and co-authored the paper

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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