data_1Dy_auto
_audit_creation_date               2022-11-24
_audit_creation_method
;
Olex2 1.5
(compiled 2021.12.09 svn.r5202d8cf for OlexSys, GUI svn.r6439)
;
_shelx_SHELXL_version_number       '2019/2'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Bourhis, L.J., Dolomanov, O.V., Gildea, R.J., Howard, J.A.K., Puschmann, H.
 (2015). Acta Cryst. A71, 59-75.

Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C20 H32 Dy Ge Si2, C18 H36 K N2 O6'
_chemical_formula_sum              'C38 H68 Dy Ge K N2 O6 Si2'
_chemical_formula_weight           979.31
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Dy' 'Dy' -9.8046 9.8477
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Ge' 'Ge' -1.0885 0.8855
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'K' 'K' 0.3868 1.0657 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si' 'Si' 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'monoclinic'
_space_group_IT_number             14
_space_group_name_H-M_alt          'P 1 21/c 1'
_space_group_name_Hall             '-P 2ybc'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, y+1/2, -z+1/2'
 '-x, -y, -z'
 'x, -y-1/2, z-1/2'

_cell_length_a                     13.1238(4)
_cell_length_b                     16.9156(4)
_cell_length_c                     20.2469(6)
_cell_angle_alpha                  90
_cell_angle_beta                   102.449(3)
_cell_angle_gamma                  90
_cell_volume                       4389.1(2)
_cell_formula_units_Z              4
_cell_measurement_reflns_used      17049
_cell_measurement_temperature      100.00(10)
_cell_measurement_theta_max        67.7830
_cell_measurement_theta_min        3.4140
_shelx_estimated_absorpt_T_max     ?
_shelx_estimated_absorpt_T_min     ?
_exptl_absorpt_coefficient_mu      11.562
_exptl_absorpt_correction_T_max    1.00000
_exptl_absorpt_correction_T_min    0.44997
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.120a (Rigaku Oxford Diffraction, 2021)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              'clear intense red'
_exptl_crystal_density_diffrn      1.482
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         plate
_exptl_crystal_F_000               2012
_exptl_crystal_size_max            0.45
_exptl_crystal_size_mid            0.35
_exptl_crystal_size_min            0.05
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0583
_diffrn_reflns_av_unetI/netI       0.0510
_diffrn_reflns_Laue_measured_fraction_full  0.981
_diffrn_reflns_Laue_measured_fraction_max  0.976
_diffrn_reflns_limit_h_max         15
_diffrn_reflns_limit_h_min         -15
_diffrn_reflns_limit_k_max         20
_diffrn_reflns_limit_k_min         -20
_diffrn_reflns_limit_l_max         24
_diffrn_reflns_limit_l_min         -23
_diffrn_reflns_number              22442
_diffrn_reflns_point_group_measured_fraction_full  0.981
_diffrn_reflns_point_group_measured_fraction_max  0.976
_diffrn_reflns_theta_full          67.684
_diffrn_reflns_theta_max           68.060
_diffrn_reflns_theta_min           3.439
_diffrn_ambient_temperature        100.15
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.981
_diffrn_measured_fraction_theta_max  0.976
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω     19.00  89.00   1.00    1.00    --    0.00  30.00-150.00   70
  2  ω    -88.00  -2.00   1.00    1.00    --    0.00  30.00-150.00   86
  3  ω   -174.00-130.00   1.00    5.00    --  -89.00  60.00  53.81   44
  4  ω    -44.00 -13.00   1.00    5.00    --  -89.00  58.00-132.30   31
  5  ω   -176.00-149.00   1.00    5.00    --  -89.00  60.00-150.90   27
  6  ω   -121.00 -50.00   1.00    5.00    --  -89.00  60.00-158.37   71
  7  ω   -144.00 -67.00   1.00    5.00    --  -89.00  58.00-132.30   77
  8  ω   -156.00 -52.00   1.00    5.00    --  -89.00  59.00 139.86  104
  9  ω   -109.00 -10.00   1.00    5.00    --  -89.00  60.00  53.81   99
 10  ω    -95.00  -3.00   1.00    5.00    --  -89.00  50.00 120.00   92
 11  ω   -101.00 -76.00   1.00    5.00    --  -89.00  60.00 -10.09   25
 12  ω   -167.00-135.00   1.00    5.00    --  -89.00  60.00 -10.09   32
;
_diffrn_measurement_device         'four-circle diffractometer'
_diffrn_measurement_device_type    'XtaLAB AFC11 (RCD3): quarter-chi single'
_diffrn_measurement_method         'ω scans'
_diffrn_radiation_type             CuK\a
_diffrn_radiation_wavelength       1.54184
_diffrn_source                     ?
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  7246
_reflns_number_total               7815
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'CrysAlisPro 1.171.41.120a (Rigaku OD, 2021)'
_computing_data_collection         'CrysAlisPro 1.171.41.120a (Rigaku OD, 2021)'
_computing_data_reduction          'CrysAlisPro 1.171.41.120a (Rigaku OD, 2021)'
_computing_molecular_graphics      'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement    'SHELXL 2019/2 (Sheldrick, 2015)'
_computing_structure_solution      'olex2.solve 1.5 (Bourhis et al., 2015)'
_refine_diff_density_max           1.181
_refine_diff_density_min           -1.089
_refine_diff_density_rms           0.140
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.128
_refine_ls_hydrogen_treatment      mixed
_refine_ls_matrix_type             full
_refine_ls_number_parameters       500
_refine_ls_number_reflns           7815
_refine_ls_number_restraints       71
_refine_ls_R_factor_all            0.0487
_refine_ls_R_factor_gt             0.0430
_refine_ls_restrained_S_all        1.133
_refine_ls_shift/su_max            0.002
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0789P)²+1.8277P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.1161
_refine_ls_wR_factor_ref           0.1261
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C18-H18
 0.835 with sigma of 0.02
3. Rigid bond restraints
 C19, C18, C17, C16, C15, C14, C13, C20
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
4. Uiso/Uaniso restraints and constraints
C19 \\sim C18 \\sim C17 \\sim C16 \\sim C15 \\sim C14 \\sim C13 \\sim C20:
within 1.7A with sigma of 0.02 and sigma for terminal atoms of 0.08 within 1.7A
Uanis(C15) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
5.a Secondary CH2 refined with riding coordinates:
 C34(H34A,H34B), C33(H33A,H33B), C31(H31A,H31B), C30(H30A,H30B), C32(H32A,
 H32B), C38(H38A,H38B), C36(H36A,H36B), C23(H23A,H23B), C24(H24A,H24B),
 C37(H37A,H37B), C21(H21A,H21B), C25(H25A,H25B), C29(H29A,H29B), C27(H27A,H27B),
  C22(H22A,H22B), C26(H26A,H26B), C28(H28A,H28B), C35(H35A,H35B)
5.b Idealised Me refined as rotating group:
 C8(H8A,H8B,H8C), C12(H12A,H12B,H12C), C10(H10A,H10B,H10C), C11(H11A,H11B,
 H11C), C9(H9A,H9B,H9C), C7(H7A,H7B,H7C), C5(H5A,H5B,H5C), C6(H6A,H6B,H6C)
;
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary       iterative
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Dy1 Dy 0.53944(2) 0.75590(2) 0.54334(2) 0.01748(11) Uani 1 1 d . . . . .
 Ge1 Ge 0.33223(3) 0.69995(2) 0.55602(2) 0.01620(13) Uani 1 1 d . . . . .
 K1 K 1.01268(5) 0.81113(4) 0.80323(4) 0.01795(18) Uani 1 1 d . . . . .
 Si2 Si 0.27929(7) 0.87786(6) 0.48459(5) 0.0191(2) Uani 1 1 d . . . . .
 Si1 Si 0.48421(7) 0.61512(6) 0.68885(5) 0.0189(2) Uani 1 1 d . . . . .
 O6 O 0.8900(2) 0.69620(16) 0.85119(13) 0.0232(6) Uani 1 1 d . . . . .
 O2 O 0.93224(19) 0.88263(15) 0.67601(13) 0.0204(5) Uani 1 1 d . . . . .
 O4 O 1.12684(19) 0.88884(16) 0.91351(13) 0.0223(6) Uani 1 1 d . . . . .
 O3 O 1.21380(19) 0.87114(18) 0.79999(13) 0.0241(6) Uani 1 1 d . . . . .
 O1 O 1.00478(19) 0.65152(16) 0.75418(13) 0.0222(6) Uani 1 1 d . . . . .
 O5 O 0.85873(18) 0.93292(16) 0.79090(12) 0.0215(6) Uani 1 1 d . . . . .
 C3 C 0.4762(3) 0.7836(2) 0.65602(19) 0.0189(8) Uani 1 1 d . . . . .
 C2 C 0.4288(3) 0.8424(2) 0.60941(19) 0.0198(8) Uani 1 1 d . . . . .
 C4 C 0.4460(3) 0.7039(2) 0.63688(19) 0.0182(8) Uani 1 1 d . . . . .
 N2 N 0.9123(2) 0.8490(2) 0.92076(16) 0.0219(7) Uani 1 1 d . . . . .
 N1 N 1.1077(2) 0.7744(2) 0.68408(17) 0.0197(7) Uani 1 1 d . . . . .
 C1 C 0.3559(3) 0.8140(2) 0.55114(18) 0.0164(7) Uani 1 1 d . . . . .
 C34 C 0.8057(3) 0.9498(3) 0.72358(19) 0.0249(8) Uani 1 1 d . . . . .
 H34A H 0.765942 0.999750 0.722413 0.030 Uiso 1 1 calc R U . . .
 H34B H 0.755967 0.906814 0.706230 0.030 Uiso 1 1 calc R U . . .
 C33 C 0.8848(3) 0.9573(2) 0.6804(2) 0.0233(8) Uani 1 1 d . . . . .
 H33A H 0.850470 0.975782 0.634611 0.028 Uiso 1 1 calc R U . . .
 H33B H 0.938614 0.996574 0.700466 0.028 Uiso 1 1 calc R U . . .
 C14 C 0.5972(4) 0.8161(4) 0.4401(3) 0.0422(12) Uani 1 1 d . U . . .
 C31 C 1.0387(3) 0.8016(2) 0.62164(19) 0.0226(8) Uani 1 1 d . . . . .
 H31A H 0.979801 0.764127 0.609137 0.027 Uiso 1 1 calc R U . . .
 H31B H 1.077720 0.801144 0.584872 0.027 Uiso 1 1 calc R U . . .
 C15 C 0.5604(4) 0.7397(4) 0.4218(3) 0.0408(13) Uani 1 1 d . U . . .
 C8 C 0.5529(3) 0.8044(2) 0.72034(19) 0.0240(8) Uani 1 1 d . . . . .
 H8A H 0.623570 0.790160 0.715952 0.036 Uiso 1 1 calc R U . . .
 H8B H 0.535414 0.775238 0.758210 0.036 Uiso 1 1 calc R U . . .
 H8C H 0.549780 0.861316 0.728706 0.036 Uiso 1 1 calc R U . . .
 C12 C 0.1937(3) 0.8159(3) 0.4176(2) 0.0320(10) Uani 1 1 d . . . . .
 H12A H 0.237422 0.781628 0.396130 0.048 Uiso 1 1 calc R U . . .
 H12B H 0.151762 0.850463 0.383394 0.048 Uiso 1 1 calc R U . . .
 H12C H 0.147425 0.783237 0.438335 0.048 Uiso 1 1 calc R U . . .
 C10 C 0.3613(3) 0.9394(2) 0.4389(2) 0.0264(9) Uani 1 1 d . . . . .
 H10A H 0.413870 0.968165 0.471837 0.040 Uiso 1 1 calc R U . . .
 H10B H 0.316713 0.977139 0.409173 0.040 Uiso 1 1 calc R U . . .
 H10C H 0.396165 0.904878 0.411689 0.040 Uiso 1 1 calc R U . . .
 C18 C 0.7021(4) 0.6687(3) 0.5682(3) 0.0439(12) Uani 1 1 d D U . . .
 C30 C 1.2113(3) 0.8135(3) 0.6922(2) 0.0269(9) Uani 1 1 d . . . . .
 H30A H 1.201090 0.867175 0.672329 0.032 Uiso 1 1 calc R U . . .
 H30B H 1.254303 0.783217 0.666442 0.032 Uiso 1 1 calc R U . . .
 C32 C 0.9958(3) 0.8837(2) 0.6271(2) 0.0258(9) Uani 1 1 d . . . . .
 H32A H 1.053874 0.921653 0.641028 0.031 Uiso 1 1 calc R U . . .
 H32B H 0.953884 0.900526 0.582698 0.031 Uiso 1 1 calc R U . . .
 C16 C 0.5768(4) 0.6653(4) 0.4515(3) 0.0453(13) Uani 1 1 d . U . . .
 C38 C 1.1215(3) 0.6877(2) 0.6828(2) 0.0249(9) Uani 1 1 d . . . . .
 H38A H 1.179644 0.672588 0.720518 0.030 Uiso 1 1 calc R U . . .
 H38B H 1.141870 0.673153 0.640051 0.030 Uiso 1 1 calc R U . . .
 C36 C 0.8491(3) 0.9216(2) 0.90679(19) 0.0224(8) Uani 1 1 d . . . . .
 H36A H 0.895826 0.968114 0.916023 0.027 Uiso 1 1 calc R U . . .
 H36B H 0.800414 0.924007 0.937879 0.027 Uiso 1 1 calc R U . . .
 C23 C 0.9001(3) 0.6167(2) 0.8322(2) 0.0245(8) Uani 1 1 d . . . . .
 H23A H 0.838279 0.585960 0.837777 0.029 Uiso 1 1 calc R U . . .
 H23B H 0.962854 0.592780 0.861268 0.029 Uiso 1 1 calc R U . . .
 C24 C 0.9093(3) 0.6147(2) 0.7594(2) 0.0247(8) Uani 1 1 d . . . . .
 H24A H 0.908149 0.559350 0.743446 0.030 Uiso 1 1 calc R U . . .
 H24B H 0.849773 0.643143 0.730846 0.030 Uiso 1 1 calc R U . . .
 C37 C 1.0260(3) 0.6404(2) 0.68841(19) 0.0242(8) Uani 1 1 d . . . . .
 H37A H 0.965321 0.658069 0.653454 0.029 Uiso 1 1 calc R U . . .
 H37B H 1.038007 0.583685 0.680942 0.029 Uiso 1 1 calc R U . . .
 C21 C 0.8457(3) 0.7838(3) 0.9336(2) 0.0290(9) Uani 1 1 d . . . . .
 H21A H 0.775633 0.790025 0.903983 0.035 Uiso 1 1 calc R U . . .
 H21B H 0.837817 0.786936 0.981092 0.035 Uiso 1 1 calc R U . . .
 C25 C 0.9991(3) 0.8603(3) 0.97838(19) 0.0257(9) Uani 1 1 d . . . . .
 H25A H 1.031854 0.808225 0.991299 0.031 Uiso 1 1 calc R U . . .
 H25B H 0.970945 0.879623 1.017020 0.031 Uiso 1 1 calc R U . . .
 C29 C 1.2696(3) 0.8203(3) 0.7639(2) 0.0280(9) Uani 1 1 d . . . . .
 H29A H 1.277447 0.767325 0.785233 0.034 Uiso 1 1 calc R U . . .
 H29B H 1.340098 0.842001 0.765460 0.034 Uiso 1 1 calc R U . . .
 C27 C 1.2105(3) 0.9380(3) 0.9034(2) 0.0263(9) Uani 1 1 d . . . . .
 H27A H 1.253649 0.954356 0.947669 0.032 Uiso 1 1 calc R U . . .
 H27B H 1.182374 0.986212 0.878194 0.032 Uiso 1 1 calc R U . . .
 C22 C 0.8880(3) 0.7031(3) 0.9216(2) 0.0284(9) Uani 1 1 d . . . . .
 H22A H 0.959291 0.696674 0.949593 0.034 Uiso 1 1 calc R U . . .
 H22B H 0.843012 0.661388 0.934429 0.034 Uiso 1 1 calc R U . . .
 C13 C 0.6619(4) 0.8485(3) 0.4958(3) 0.0384(11) Uani 1 1 d . U . . .
 C19 C 0.7367(4) 0.7458(4) 0.5876(3) 0.0415(13) Uani 1 1 d . U . . .
 C11 C 0.1910(3) 0.9476(3) 0.5198(2) 0.0292(9) Uani 1 1 d . . . . .
 H11A H 0.137278 0.917053 0.535338 0.044 Uiso 1 1 calc R U . . .
 H11B H 0.157766 0.984513 0.484324 0.044 Uiso 1 1 calc R U . . .
 H11C H 0.232500 0.977271 0.557800 0.044 Uiso 1 1 calc R U . . .
 C9 C 0.4520(3) 0.9300(2) 0.6239(2) 0.0238(8) Uani 1 1 d . . . . .
 H9A H 0.527571 0.937845 0.637673 0.036 Uiso 1 1 calc R U . . .
 H9B H 0.418730 0.947413 0.660380 0.036 Uiso 1 1 calc R U . . .
 H9C H 0.424492 0.960947 0.583042 0.036 Uiso 1 1 calc R U . . .
 C26 C 1.0829(3) 0.9171(2) 0.9672(2) 0.0249(8) Uani 1 1 d . . . . .
 H26A H 1.052312 0.970134 0.955827 0.030 Uiso 1 1 calc R U . . .
 H26B H 1.137858 0.921513 1.008989 0.030 Uiso 1 1 calc R U . . .
 C20 C 0.7181(4) 0.8201(3) 0.5562(3) 0.0419(12) Uani 1 1 d . U . . .
 C7 C 0.6245(3) 0.6053(3) 0.7341(2) 0.0363(11) Uani 1 1 d . . . . .
 H7A H 0.669321 0.608203 0.701167 0.054 Uiso 1 1 calc R U . . .
 H7B H 0.634885 0.554371 0.757589 0.054 Uiso 1 1 calc R U . . .
 H7C H 0.642519 0.648273 0.766984 0.054 Uiso 1 1 calc R U . . .
 C28 C 1.2758(3) 0.8926(3) 0.8642(2) 0.0275(9) Uani 1 1 d . . . . .
 H28A H 1.335520 0.925348 0.857993 0.033 Uiso 1 1 calc R U . . .
 H28B H 1.303732 0.844368 0.889539 0.033 Uiso 1 1 calc R U . . .
 C35 C 0.7875(3) 0.9259(3) 0.8350(2) 0.0269(9) Uani 1 1 d . . . . .
 H35A H 0.744657 0.877602 0.823834 0.032 Uiso 1 1 calc R U . . .
 H35B H 0.740214 0.972152 0.829436 0.032 Uiso 1 1 calc R U . . .
 C5 C 0.4068(3) 0.6077(2) 0.7568(2) 0.0253(8) Uani 1 1 d . . . . .
 H5A H 0.421460 0.653777 0.786687 0.038 Uiso 1 1 calc R U . . .
 H5B H 0.426434 0.559381 0.783147 0.038 Uiso 1 1 calc R U . . .
 H5C H 0.332147 0.606129 0.735905 0.038 Uiso 1 1 calc R U . . .
 C17 C 0.6356(4) 0.6345(3) 0.5121(3) 0.0456(12) Uani 1 1 d . U . . .
 C6 C 0.4558(3) 0.5255(2) 0.6337(2) 0.0273(9) Uani 1 1 d . . . . .
 H6A H 0.383259 0.527292 0.608347 0.041 Uiso 1 1 calc R U . . .
 H6B H 0.466733 0.477862 0.661850 0.041 Uiso 1 1 calc R U . . .
 H6C H 0.502638 0.524484 0.601953 0.041 Uiso 1 1 calc R U . . .
 H15 H 0.521(4) 0.746(2) 0.387(3) 0.004(10) Uiso 1 1 d . . . . .
 H14 H 0.567(4) 0.852(3) 0.407(3) 0.042(14) Uiso 1 1 d . . . . .
 H17 H 0.626(4) 0.586(4) 0.518(3) 0.043(15) Uiso 1 1 d . . . . .
 H13 H 0.656(4) 0.908(3) 0.495(2) 0.038(13) Uiso 1 1 d . . . . .
 H16 H 0.542(5) 0.627(4) 0.435(3) 0.051(17) Uiso 1 1 d . . . . .
 H20 H 0.750(5) 0.864(4) 0.581(3) 0.061(18) Uiso 1 1 d . . . . .
 H19 H 0.776(6) 0.754(3) 0.626(4) 0.06(2) Uiso 1 1 d . . . . .
 H18 H 0.727(5) 0.637(3) 0.598(2) 0.06(2) Uiso 1 1 d D . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Dy1 C3 2.632(4) . ?
 Dy1 C2 2.623(4) . ?
 Dy1 C4 2.620(4) . ?
 Dy1 C1 2.637(4) . ?
 Dy1 C14 2.582(5) . ?
 Dy1 C15 2.549(5) . ?
 Dy1 C18 2.553(4) . ?
 Dy1 C16 2.538(5) . ?
 Dy1 C13 2.575(5) . ?
 Dy1 C19 2.556(5) . ?
 Dy1 C20 2.546(4) . ?
 Dy1 C17 2.561(5) . ?
 Ge1 C4 1.965(4) . ?
 Ge1 C1 1.959(4) . ?
 K1 O6 2.827(3) . ?
 K1 O2 2.835(3) . ?
 K1 O4 2.741(3) . ?
 K1 O3 2.842(3) . ?
 K1 O1 2.871(3) . ?
 K1 O5 2.858(3) . ?
 K1 N2 3.027(3) . ?
 K1 N1 3.010(3) . ?
 Si2 C1 1.847(4) . ?
 Si2 C12 1.883(4) . ?
 Si2 C10 1.878(4) . ?
 Si2 C11 1.896(4) . ?
 Si1 C4 1.841(4) . ?
 Si1 C7 1.879(4) . ?
 Si1 C5 1.882(4) . ?
 Si1 C6 1.872(4) . ?
 O6 C23 1.413(5) . ?
 O6 C22 1.437(5) . ?
 O2 C33 1.420(4) . ?
 O2 C32 1.425(4) . ?
 O4 C27 1.427(5) . ?
 O4 C26 1.418(5) . ?
 O3 C29 1.429(5) . ?
 O3 C28 1.424(5) . ?
 O1 C24 1.423(5) . ?
 O1 C37 1.430(5) . ?
 O5 C34 1.420(5) . ?
 O5 C35 1.430(4) . ?
 C3 C2 1.420(6) . ?
 C3 C4 1.435(6) . ?
 C3 C8 1.506(5) . ?
 C2 C1 1.432(5) . ?
 C2 C9 1.528(5) . ?
 N2 C36 1.474(5) . ?
 N2 C21 1.465(5) . ?
 N2 C25 1.457(5) . ?
 N1 C31 1.462(5) . ?
 N1 C30 1.489(5) . ?
 N1 C38 1.479(5) . ?
 C34 H34A 0.9900 . ?
 C34 H34B 0.9900 . ?
 C34 C33 1.500(5) . ?
 C33 H33A 0.9900 . ?
 C33 H33B 0.9900 . ?
 C14 C15 1.401(8) . ?
 C14 C13 1.372(8) . ?
 C14 H14 0.92(6) . ?
 C31 H31A 0.9900 . ?
 C31 H31B 0.9900 . ?
 C31 C32 1.511(5) . ?
 C15 C16 1.392(9) . ?
 C15 H15 0.79(5) . ?
 C8 H8A 0.9800 . ?
 C8 H8B 0.9800 . ?
 C8 H8C 0.9800 . ?
 C12 H12A 0.9800 . ?
 C12 H12B 0.9800 . ?
 C12 H12C 0.9800 . ?
 C10 H10A 0.9800 . ?
 C10 H10B 0.9800 . ?
 C10 H10C 0.9800 . ?
 C18 C19 1.408(8) . ?
 C18 C17 1.400(9) . ?
 C18 H18 0.83(2) . ?
 C30 H30A 0.9900 . ?
 C30 H30B 0.9900 . ?
 C30 C29 1.492(6) . ?
 C32 H32A 0.9900 . ?
 C32 H32B 0.9900 . ?
 C16 C17 1.401(9) . ?
 C16 H16 0.82(6) . ?
 C38 H38A 0.9900 . ?
 C38 H38B 0.9900 . ?
 C38 C37 1.512(6) . ?
 C36 H36A 0.9900 . ?
 C36 H36B 0.9900 . ?
 C36 C35 1.505(6) . ?
 C23 H23A 0.9900 . ?
 C23 H23B 0.9900 . ?
 C23 C24 1.505(6) . ?
 C24 H24A 0.9900 . ?
 C24 H24B 0.9900 . ?
 C37 H37A 0.9900 . ?
 C37 H37B 0.9900 . ?
 C21 H21A 0.9900 . ?
 C21 H21B 0.9900 . ?
 C21 C22 1.512(6) . ?
 C25 H25A 0.9900 . ?
 C25 H25B 0.9900 . ?
 C25 C26 1.514(6) . ?
 C29 H29A 0.9900 . ?
 C29 H29B 0.9900 . ?
 C27 H27A 0.9900 . ?
 C27 H27B 0.9900 . ?
 C27 C28 1.500(6) . ?
 C22 H22A 0.9900 . ?
 C22 H22B 0.9900 . ?
 C13 C20 1.373(8) . ?
 C13 H13 1.00(6) . ?
 C19 C20 1.406(8) . ?
 C19 H19 0.85(8) . ?
 C11 H11A 0.9800 . ?
 C11 H11B 0.9800 . ?
 C11 H11C 0.9800 . ?
 C9 H9A 0.9800 . ?
 C9 H9B 0.9800 . ?
 C9 H9C 0.9800 . ?
 C26 H26A 0.9900 . ?
 C26 H26B 0.9900 . ?
 C20 H20 0.95(7) . ?
 C7 H7A 0.9800 . ?
 C7 H7B 0.9800 . ?
 C7 H7C 0.9800 . ?
 C28 H28A 0.9900 . ?
 C28 H28B 0.9900 . ?
 C35 H35A 0.9900 . ?
 C35 H35B 0.9900 . ?
 C5 H5A 0.9800 . ?
 C5 H5B 0.9800 . ?
 C5 H5C 0.9800 . ?
 C17 H17 0.84(6) . ?
 C6 H6A 0.9800 . ?
 C6 H6B 0.9800 . ?
 C6 H6C 0.9800 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 C3 Dy1 C1 54.50(12) . . ?
 C2 Dy1 C3 31.34(12) . . ?
 C2 Dy1 C1 31.60(12) . . ?
 C4 Dy1 C3 31.71(12) . . ?
 C4 Dy1 C2 54.67(11) . . ?
 C4 Dy1 C1 60.39(11) . . ?
 C14 Dy1 C3 146.52(16) . . ?
 C14 Dy1 C2 118.98(14) . . ?
 C14 Dy1 C4 169.27(14) . . ?
 C14 Dy1 C1 109.45(13) . . ?
 C15 Dy1 C3 167.31(15) . . ?
 C15 Dy1 C2 137.66(15) . . ?
 C15 Dy1 C4 145.73(16) . . ?
 C15 Dy1 C1 112.82(14) . . ?
 C15 Dy1 C14 31.68(18) . . ?
 C15 Dy1 C18 82.45(17) . . ?
 C15 Dy1 C13 59.91(19) . . ?
 C15 Dy1 C19 91.10(17) . . ?
 C15 Dy1 C17 60.89(19) . . ?
 C18 Dy1 C3 109.77(14) . . ?
 C18 Dy1 C2 138.85(16) . . ?
 C18 Dy1 C4 99.51(13) . . ?
 C18 Dy1 C1 159.83(13) . . ?
 C18 Dy1 C14 90.49(15) . . ?
 C18 Dy1 C13 82.11(16) . . ?
 C18 Dy1 C19 31.99(19) . . ?
 C18 Dy1 C17 31.8(2) . . ?
 C16 Dy1 C3 152.79(17) . . ?
 C16 Dy1 C2 157.87(15) . . ?
 C16 Dy1 C4 121.42(16) . . ?
 C16 Dy1 C1 126.29(15) . . ?
 C16 Dy1 C14 60.5(2) . . ?
 C16 Dy1 C15 31.75(19) . . ?
 C16 Dy1 C18 60.7(2) . . ?
 C16 Dy1 C13 81.90(17) . . ?
 C16 Dy1 C19 82.84(17) . . ?
 C16 Dy1 C20 90.80(16) . . ?
 C16 Dy1 C17 31.9(2) . . ?
 C13 Dy1 C3 123.66(15) . . ?
 C13 Dy1 C2 108.05(14) . . ?
 C13 Dy1 C4 154.35(15) . . ?
 C13 Dy1 C1 116.58(13) . . ?
 C13 Dy1 C14 30.86(19) . . ?
 C19 Dy1 C3 101.12(14) . . ?
 C19 Dy1 C2 119.28(15) . . ?
 C19 Dy1 C4 108.71(15) . . ?
 C19 Dy1 C1 150.82(15) . . ?
 C19 Dy1 C14 81.86(17) . . ?
 C19 Dy1 C13 60.35(18) . . ?
 C19 Dy1 C17 61.11(19) . . ?
 C20 Dy1 C3 106.88(14) . . ?
 C20 Dy1 C2 107.97(14) . . ?
 C20 Dy1 C4 129.28(16) . . ?
 C20 Dy1 C1 131.90(15) . . ?
 C20 Dy1 C14 59.36(19) . . ?
 C20 Dy1 C15 81.75(18) . . ?
 C20 Dy1 C18 60.9(2) . . ?
 C20 Dy1 C13 31.09(19) . . ?
 C20 Dy1 C19 31.99(18) . . ?
 C20 Dy1 C17 82.85(17) . . ?
 C17 Dy1 C3 128.43(16) . . ?
 C17 Dy1 C2 158.50(15) . . ?
 C17 Dy1 C4 104.01(14) . . ?
 C17 Dy1 C1 144.96(15) . . ?
 C17 Dy1 C14 82.51(17) . . ?
 C17 Dy1 C13 90.86(14) . . ?
 C4 Ge1 Dy1 60.72(10) . . ?
 C1 Ge1 Dy1 61.27(10) . . ?
 C1 Ge1 C4 84.71(15) . . ?
 O6 K1 O2 118.52(8) . . ?
 O6 K1 O3 148.68(8) . . ?
 O6 K1 O1 59.42(8) . . ?
 O6 K1 O5 94.67(8) . . ?
 O6 K1 N2 59.93(9) . . ?
 O6 K1 N1 119.91(9) . . ?
 O2 K1 O3 89.57(8) . . ?
 O2 K1 O1 96.22(8) . . ?
 O2 K1 O5 59.71(7) . . ?
 O2 K1 N2 118.94(8) . . ?
 O2 K1 N1 59.83(8) . . ?
 O4 K1 O6 107.56(8) . . ?
 O4 K1 O2 124.50(8) . . ?
 O4 K1 O3 60.02(8) . . ?
 O4 K1 O1 134.85(8) . . ?
 O4 K1 O5 88.71(8) . . ?
 O4 K1 N2 60.80(8) . . ?
 O4 K1 N1 120.24(9) . . ?
 O3 K1 O1 107.00(8) . . ?
 O3 K1 O5 112.53(8) . . ?
 O3 K1 N2 120.42(9) . . ?
 O3 K1 N1 60.51(8) . . ?
 O1 K1 N2 118.80(9) . . ?
 O1 K1 N1 61.25(9) . . ?
 O5 K1 O1 132.49(8) . . ?
 O5 K1 N2 59.78(8) . . ?
 O5 K1 N1 119.08(8) . . ?
 N1 K1 N2 178.65(9) . . ?
 C1 Si2 C12 110.25(18) . . ?
 C1 Si2 C10 113.83(17) . . ?
 C1 Si2 C11 111.76(18) . . ?
 C12 Si2 C11 107.4(2) . . ?
 C10 Si2 C12 105.6(2) . . ?
 C10 Si2 C11 107.57(18) . . ?
 C4 Si1 C7 117.90(19) . . ?
 C4 Si1 C5 110.41(17) . . ?
 C4 Si1 C6 108.97(18) . . ?
 C7 Si1 C5 105.36(19) . . ?
 C6 Si1 C7 105.5(2) . . ?
 C6 Si1 C5 108.23(19) . . ?
 C23 O6 K1 117.9(2) . . ?
 C23 O6 C22 111.8(3) . . ?
 C22 O6 K1 114.8(2) . . ?
 C33 O2 K1 113.9(2) . . ?
 C33 O2 C32 111.3(3) . . ?
 C32 O2 K1 118.5(2) . . ?
 C27 O4 K1 117.7(2) . . ?
 C26 O4 K1 123.0(2) . . ?
 C26 O4 C27 111.5(3) . . ?
 C29 O3 K1 112.2(2) . . ?
 C28 O3 K1 114.9(2) . . ?
 C28 O3 C29 111.4(3) . . ?
 C24 O1 K1 110.6(2) . . ?
 C24 O1 C37 111.3(3) . . ?
 C37 O1 K1 116.5(2) . . ?
 C34 O5 K1 114.8(2) . . ?
 C34 O5 C35 111.4(3) . . ?
 C35 O5 K1 115.5(2) . . ?
 C2 C3 Dy1 74.0(2) . . ?
 C2 C3 C4 115.0(3) . . ?
 C2 C3 C8 121.8(4) . . ?
 C4 C3 Dy1 73.7(2) . . ?
 C4 C3 C8 123.2(4) . . ?
 C8 C3 Dy1 121.0(2) . . ?
 C3 C2 Dy1 74.7(2) . . ?
 C3 C2 C1 115.5(3) . . ?
 C3 C2 C9 120.7(3) . . ?
 C1 C2 Dy1 74.7(2) . . ?
 C1 C2 C9 123.7(3) . . ?
 C9 C2 Dy1 122.0(2) . . ?
 Ge1 C4 Dy1 78.42(12) . . ?
 Si1 C4 Dy1 125.10(17) . . ?
 Si1 C4 Ge1 120.8(2) . . ?
 C3 C4 Dy1 74.62(19) . . ?
 C3 C4 Ge1 111.9(3) . . ?
 C3 C4 Si1 126.0(3) . . ?
 C36 N2 K1 110.3(2) . . ?
 C21 N2 K1 110.9(2) . . ?
 C21 N2 C36 109.2(3) . . ?
 C25 N2 K1 105.1(2) . . ?
 C25 N2 C36 110.8(3) . . ?
 C25 N2 C21 110.4(3) . . ?
 C31 N1 K1 110.0(2) . . ?
 C31 N1 C30 109.7(3) . . ?
 C31 N1 C38 110.6(3) . . ?
 C30 N1 K1 110.2(2) . . ?
 C38 N1 K1 107.0(2) . . ?
 C38 N1 C30 109.3(3) . . ?
 Ge1 C1 Dy1 78.08(12) . . ?
 Si2 C1 Dy1 122.34(17) . . ?
 Si2 C1 Ge1 123.06(19) . . ?
 C2 C1 Dy1 73.7(2) . . ?
 C2 C1 Ge1 112.0(3) . . ?
 C2 C1 Si2 124.4(3) . . ?
 O5 C34 H34A 110.0 . . ?
 O5 C34 H34B 110.0 . . ?
 O5 C34 C33 108.6(3) . . ?
 H34A C34 H34B 108.4 . . ?
 C33 C34 H34A 110.0 . . ?
 C33 C34 H34B 110.0 . . ?
 O2 C33 C34 109.2(3) . . ?
 O2 C33 H33A 109.8 . . ?
 O2 C33 H33B 109.8 . . ?
 C34 C33 H33A 109.8 . . ?
 C34 C33 H33B 109.8 . . ?
 H33A C33 H33B 108.3 . . ?
 Dy1 C14 H14 134(3) . . ?
 C15 C14 Dy1 72.9(3) . . ?
 C15 C14 H14 110(3) . . ?
 C13 C14 Dy1 74.3(3) . . ?
 C13 C14 C15 134.7(5) . . ?
 C13 C14 H14 115(3) . . ?
 N1 C31 H31A 108.9 . . ?
 N1 C31 H31B 108.9 . . ?
 N1 C31 C32 113.4(3) . . ?
 H31A C31 H31B 107.7 . . ?
 C32 C31 H31A 108.9 . . ?
 C32 C31 H31B 108.9 . . ?
 Dy1 C15 H15 132(3) . . ?
 C14 C15 Dy1 75.4(3) . . ?
 C14 C15 H15 104(3) . . ?
 C16 C15 Dy1 73.7(3) . . ?
 C16 C15 C14 135.1(5) . . ?
 C16 C15 H15 121(3) . . ?
 C3 C8 H8A 109.5 . . ?
 C3 C8 H8B 109.5 . . ?
 C3 C8 H8C 109.5 . . ?
 H8A C8 H8B 109.5 . . ?
 H8A C8 H8C 109.5 . . ?
 H8B C8 H8C 109.5 . . ?
 Si2 C12 H12A 109.5 . . ?
 Si2 C12 H12B 109.5 . . ?
 Si2 C12 H12C 109.5 . . ?
 H12A C12 H12B 109.5 . . ?
 H12A C12 H12C 109.5 . . ?
 H12B C12 H12C 109.5 . . ?
 Si2 C10 H10A 109.5 . . ?
 Si2 C10 H10B 109.5 . . ?
 Si2 C10 H10C 109.5 . . ?
 H10A C10 H10B 109.5 . . ?
 H10A C10 H10C 109.5 . . ?
 H10B C10 H10C 109.5 . . ?
 Dy1 C18 H18 134(5) . . ?
 C19 C18 Dy1 74.1(3) . . ?
 C19 C18 H18 110(5) . . ?
 C17 C18 Dy1 74.4(3) . . ?
 C17 C18 C19 135.8(5) . . ?
 C17 C18 H18 114(5) . . ?
 N1 C30 H30A 108.8 . . ?
 N1 C30 H30B 108.8 . . ?
 N1 C30 C29 113.9(3) . . ?
 H30A C30 H30B 107.7 . . ?
 C29 C30 H30A 108.8 . . ?
 C29 C30 H30B 108.8 . . ?
 O2 C32 C31 108.8(3) . . ?
 O2 C32 H32A 109.9 . . ?
 O2 C32 H32B 109.9 . . ?
 C31 C32 H32A 109.9 . . ?
 C31 C32 H32B 109.9 . . ?
 H32A C32 H32B 108.3 . . ?
 Dy1 C16 H16 126(4) . . ?
 C15 C16 Dy1 74.6(3) . . ?
 C15 C16 C17 136.0(5) . . ?
 C15 C16 H16 121(4) . . ?
 C17 C16 Dy1 74.9(3) . . ?
 C17 C16 H16 102(4) . . ?
 N1 C38 H38A 108.6 . . ?
 N1 C38 H38B 108.6 . . ?
 N1 C38 C37 114.6(3) . . ?
 H38A C38 H38B 107.6 . . ?
 C37 C38 H38A 108.6 . . ?
 C37 C38 H38B 108.6 . . ?
 N2 C36 H36A 109.0 . . ?
 N2 C36 H36B 109.0 . . ?
 N2 C36 C35 112.9(3) . . ?
 H36A C36 H36B 107.8 . . ?
 C35 C36 H36A 109.0 . . ?
 C35 C36 H36B 109.0 . . ?
 O6 C23 H23A 110.0 . . ?
 O6 C23 H23B 110.0 . . ?
 O6 C23 C24 108.6(3) . . ?
 H23A C23 H23B 108.3 . . ?
 C24 C23 H23A 110.0 . . ?
 C24 C23 H23B 110.0 . . ?
 O1 C24 C23 108.7(3) . . ?
 O1 C24 H24A 109.9 . . ?
 O1 C24 H24B 109.9 . . ?
 C23 C24 H24A 109.9 . . ?
 C23 C24 H24B 109.9 . . ?
 H24A C24 H24B 108.3 . . ?
 O1 C37 C38 109.4(3) . . ?
 O1 C37 H37A 109.8 . . ?
 O1 C37 H37B 109.8 . . ?
 C38 C37 H37A 109.8 . . ?
 C38 C37 H37B 109.8 . . ?
 H37A C37 H37B 108.2 . . ?
 N2 C21 H21A 108.9 . . ?
 N2 C21 H21B 108.9 . . ?
 N2 C21 C22 113.4(3) . . ?
 H21A C21 H21B 107.7 . . ?
 C22 C21 H21A 108.9 . . ?
 C22 C21 H21B 108.9 . . ?
 N2 C25 H25A 108.4 . . ?
 N2 C25 H25B 108.4 . . ?
 N2 C25 C26 115.5(3) . . ?
 H25A C25 H25B 107.5 . . ?
 C26 C25 H25A 108.4 . . ?
 C26 C25 H25B 108.4 . . ?
 O3 C29 C30 109.4(3) . . ?
 O3 C29 H29A 109.8 . . ?
 O3 C29 H29B 109.8 . . ?
 C30 C29 H29A 109.8 . . ?
 C30 C29 H29B 109.8 . . ?
 H29A C29 H29B 108.2 . . ?
 O4 C27 H27A 109.9 . . ?
 O4 C27 H27B 109.9 . . ?
 O4 C27 C28 108.8(3) . . ?
 H27A C27 H27B 108.3 . . ?
 C28 C27 H27A 109.9 . . ?
 C28 C27 H27B 109.9 . . ?
 O6 C22 C21 108.6(3) . . ?
 O6 C22 H22A 110.0 . . ?
 O6 C22 H22B 110.0 . . ?
 C21 C22 H22A 110.0 . . ?
 C21 C22 H22B 110.0 . . ?
 H22A C22 H22B 108.3 . . ?
 Dy1 C13 H13 124(3) . . ?
 C14 C13 Dy1 74.8(3) . . ?
 C14 C13 C20 135.4(5) . . ?
 C14 C13 H13 111(3) . . ?
 C20 C13 Dy1 73.3(3) . . ?
 C20 C13 H13 113(3) . . ?
 Dy1 C19 H19 132(5) . . ?
 C18 C19 Dy1 73.9(3) . . ?
 C18 C19 H19 120(4) . . ?
 C20 C19 Dy1 73.6(3) . . ?
 C20 C19 C18 133.5(5) . . ?
 C20 C19 H19 106(4) . . ?
 Si2 C11 H11A 109.5 . . ?
 Si2 C11 H11B 109.5 . . ?
 Si2 C11 H11C 109.5 . . ?
 H11A C11 H11B 109.5 . . ?
 H11A C11 H11C 109.5 . . ?
 H11B C11 H11C 109.5 . . ?
 C2 C9 H9A 109.5 . . ?
 C2 C9 H9B 109.5 . . ?
 C2 C9 H9C 109.5 . . ?
 H9A C9 H9B 109.5 . . ?
 H9A C9 H9C 109.5 . . ?
 H9B C9 H9C 109.5 . . ?
 O4 C26 C25 109.3(3) . . ?
 O4 C26 H26A 109.8 . . ?
 O4 C26 H26B 109.8 . . ?
 C25 C26 H26A 109.8 . . ?
 C25 C26 H26B 109.8 . . ?
 H26A C26 H26B 108.3 . . ?
 Dy1 C20 H20 133(4) . . ?
 C13 C20 Dy1 75.6(3) . . ?
 C13 C20 C19 136.3(5) . . ?
 C13 C20 H20 107(4) . . ?
 C19 C20 Dy1 74.4(3) . . ?
 C19 C20 H20 116(4) . . ?
 Si1 C7 H7A 109.5 . . ?
 Si1 C7 H7B 109.5 . . ?
 Si1 C7 H7C 109.5 . . ?
 H7A C7 H7B 109.5 . . ?
 H7A C7 H7C 109.5 . . ?
 H7B C7 H7C 109.5 . . ?
 O3 C28 C27 109.5(3) . . ?
 O3 C28 H28A 109.8 . . ?
 O3 C28 H28B 109.8 . . ?
 C27 C28 H28A 109.8 . . ?
 C27 C28 H28B 109.8 . . ?
 H28A C28 H28B 108.2 . . ?
 O5 C35 C36 108.6(3) . . ?
 O5 C35 H35A 110.0 . . ?
 O5 C35 H35B 110.0 . . ?
 C36 C35 H35A 110.0 . . ?
 C36 C35 H35B 110.0 . . ?
 H35A C35 H35B 108.3 . . ?
 Si1 C5 H5A 109.5 . . ?
 Si1 C5 H5B 109.5 . . ?
 Si1 C5 H5C 109.5 . . ?
 H5A C5 H5B 109.5 . . ?
 H5A C5 H5C 109.5 . . ?
 H5B C5 H5C 109.5 . . ?
 Dy1 C17 H17 130(4) . . ?
 C18 C17 Dy1 73.8(3) . . ?
 C18 C17 C16 133.3(5) . . ?
 C18 C17 H17 112(4) . . ?
 C16 C17 Dy1 73.2(3) . . ?
 C16 C17 H17 114(4) . . ?
 Si1 C6 H6A 109.5 . . ?
 Si1 C6 H6B 109.5 . . ?
 Si1 C6 H6C 109.5 . . ?
 H6A C6 H6B 109.5 . . ?
 H6A C6 H6C 109.5 . . ?
 H6B C6 H6C 109.5 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 Dy1 C3 C2 C1 64.3(3) . . . . ?
 Dy1 C3 C2 C9 -118.4(3) . . . . ?
 Dy1 C3 C4 Ge1 -70.42(18) . . . . ?
 Dy1 C3 C4 Si1 122.5(3) . . . . ?
 Dy1 C2 C1 Ge1 69.47(18) . . . . ?
 Dy1 C2 C1 Si2 -118.4(3) . . . . ?
 Dy1 C14 C15 C16 -47.8(6) . . . . ?
 Dy1 C14 C13 C20 45.7(5) . . . . ?
 Dy1 C15 C16 C17 -47.7(6) . . . . ?
 Dy1 C18 C19 C20 -47.3(6) . . . . ?
 Dy1 C18 C17 C16 46.5(5) . . . . ?
 Dy1 C16 C17 C18 -46.7(5) . . . . ?
 Dy1 C13 C20 C19 47.9(6) . . . . ?
 Dy1 C19 C20 C13 -48.3(6) . . . . ?
 K1 O6 C23 C24 -39.9(4) . . . . ?
 K1 O6 C22 C21 59.0(4) . . . . ?
 K1 O2 C33 C34 -52.2(3) . . . . ?
 K1 O2 C32 C31 48.5(4) . . . . ?
 K1 O4 C27 C28 -48.8(4) . . . . ?
 K1 O4 C26 C25 35.0(4) . . . . ?
 K1 O3 C29 C30 61.7(4) . . . . ?
 K1 O3 C28 C27 -44.6(4) . . . . ?
 K1 O1 C24 C23 -58.1(3) . . . . ?
 K1 O1 C37 C38 45.9(4) . . . . ?
 K1 O5 C34 C33 -46.9(4) . . . . ?
 K1 O5 C35 C36 55.9(4) . . . . ?
 K1 N2 C36 C35 41.2(4) . . . . ?
 K1 N2 C21 C22 35.6(4) . . . . ?
 K1 N2 C25 C26 51.0(3) . . . . ?
 K1 N1 C31 C32 45.0(3) . . . . ?
 K1 N1 C30 C29 32.7(4) . . . . ?
 K1 N1 C38 C37 49.3(3) . . . . ?
 O6 C23 C24 O1 66.2(4) . . . . ?
 O4 C27 C28 O3 61.1(4) . . . . ?
 O5 C34 C33 O2 66.6(4) . . . . ?
 C3 C2 C1 Dy1 -64.3(3) . . . . ?
 C3 C2 C1 Ge1 5.2(4) . . . . ?
 C3 C2 C1 Si2 177.4(3) . . . . ?
 C2 C3 C4 Dy1 63.0(3) . . . . ?
 C2 C3 C4 Ge1 -7.4(4) . . . . ?
 C2 C3 C4 Si1 -174.5(3) . . . . ?
 C4 C3 C2 Dy1 -62.8(3) . . . . ?
 C4 C3 C2 C1 1.5(5) . . . . ?
 C4 C3 C2 C9 178.7(3) . . . . ?
 N2 C36 C35 O5 -66.3(4) . . . . ?
 N2 C21 C22 O6 -64.0(5) . . . . ?
 N2 C25 C26 O4 -60.3(4) . . . . ?
 N1 C31 C32 O2 -63.6(4) . . . . ?
 N1 C30 C29 O3 -64.8(5) . . . . ?
 N1 C38 C37 O1 -67.1(4) . . . . ?
 C34 O5 C35 C36 -170.7(3) . . . . ?
 C33 O2 C32 C31 -176.6(3) . . . . ?
 C14 C15 C16 Dy1 48.4(6) . . . . ?
 C14 C15 C16 C17 0.7(10) . . . . ?
 C14 C13 C20 Dy1 -46.1(5) . . . . ?
 C14 C13 C20 C19 1.8(10) . . . . ?
 C31 N1 C30 C29 153.9(3) . . . . ?
 C31 N1 C38 C37 -70.5(4) . . . . ?
 C15 C14 C13 Dy1 -44.9(5) . . . . ?
 C15 C14 C13 C20 0.7(9) . . . . ?
 C15 C16 C17 Dy1 47.5(6) . . . . ?
 C15 C16 C17 C18 0.8(9) . . . . ?
 C8 C3 C2 Dy1 116.8(3) . . . . ?
 C8 C3 C2 C1 -178.8(3) . . . . ?
 C8 C3 C2 C9 -1.6(5) . . . . ?
 C8 C3 C4 Dy1 -116.7(3) . . . . ?
 C8 C3 C4 Ge1 172.9(3) . . . . ?
 C8 C3 C4 Si1 5.8(5) . . . . ?
 C12 Si2 C1 Dy1 88.2(2) . . . . ?
 C12 Si2 C1 Ge1 -8.7(3) . . . . ?
 C12 Si2 C1 C2 179.9(3) . . . . ?
 C10 Si2 C1 Dy1 -30.3(3) . . . . ?
 C10 Si2 C1 Ge1 -127.2(2) . . . . ?
 C10 Si2 C1 C2 61.5(4) . . . . ?
 C18 C19 C20 Dy1 47.3(6) . . . . ?
 C18 C19 C20 C13 -0.9(10) . . . . ?
 C30 N1 C31 C32 -76.4(4) . . . . ?
 C30 N1 C38 C37 168.7(3) . . . . ?
 C32 O2 C33 C34 170.8(3) . . . . ?
 C38 N1 C31 C32 163.0(3) . . . . ?
 C38 N1 C30 C29 -84.7(4) . . . . ?
 C36 N2 C21 C22 157.5(3) . . . . ?
 C36 N2 C25 C26 -68.2(4) . . . . ?
 C23 O6 C22 C21 -163.4(3) . . . . ?
 C24 O1 C37 C38 173.9(3) . . . . ?
 C37 O1 C24 C23 170.8(3) . . . . ?
 C21 N2 C36 C35 -81.0(4) . . . . ?
 C21 N2 C25 C26 170.7(3) . . . . ?
 C25 N2 C36 C35 157.2(3) . . . . ?
 C25 N2 C21 C22 -80.5(4) . . . . ?
 C29 O3 C28 C27 -173.5(3) . . . . ?
 C27 O4 C26 C25 -176.7(3) . . . . ?
 C22 O6 C23 C24 -176.0(3) . . . . ?
 C13 C14 C15 Dy1 45.4(5) . . . . ?
 C13 C14 C15 C16 -2.5(10) . . . . ?
 C19 C18 C17 Dy1 -46.1(5) . . . . ?
 C19 C18 C17 C16 0.5(9) . . . . ?
 C11 Si2 C1 Dy1 -152.4(2) . . . . ?
 C11 Si2 C1 Ge1 110.7(2) . . . . ?
 C11 Si2 C1 C2 -60.7(4) . . . . ?
 C9 C2 C1 Dy1 118.6(3) . . . . ?
 C9 C2 C1 Ge1 -172.0(3) . . . . ?
 C9 C2 C1 Si2 0.2(5) . . . . ?
 C26 O4 C27 C28 161.1(3) . . . . ?
 C7 Si1 C4 Dy1 51.6(3) . . . . ?
 C7 Si1 C4 Ge1 149.2(2) . . . . ?
 C7 Si1 C4 C3 -44.7(4) . . . . ?
 C28 O3 C29 C30 -167.9(3) . . . . ?
 C35 O5 C34 C33 179.3(3) . . . . ?
 C5 Si1 C4 Dy1 172.7(2) . . . . ?
 C5 Si1 C4 Ge1 -89.6(2) . . . . ?
 C5 Si1 C4 C3 76.4(3) . . . . ?
 C17 C18 C19 Dy1 46.1(5) . . . . ?
 C17 C18 C19 C20 -1.1(10) . . . . ?
 C6 Si1 C4 Dy1 -68.6(2) . . . . ?
 C6 Si1 C4 Ge1 29.1(3) . . . . ?
 C6 Si1 C4 C3 -164.8(3) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
